| Numerical evaluation of NOx mechanisms in methane-air counterflow premixed flames Eun-Seong Cho
The Journal of Mechanical Science and Technology, vol. 23, no. 3, pp.659-666, 2009
Abstract : The control of nitrogen oxides (NOx) has been a major issue in designing combustion systems, since NOx play a key
role in ozone depletion and the generation of photochemical smog. The characteristics of NOx emission can be essential
information for the development of a clean combustor having suitable reduction methodologies. In the present study,
NOx emission characteristics were evaluated numerically, accounting for the effect of equivalence ratio, stretch rate,
pressure, and initial temperature. In general, peak NOx emission appeared near the equivalence ratio of unity case, and
NOx emission increased with pressure and initial temperature due to the temperature sensitivity in NOx mechanism.
NOx decreased with stretch rate due to the decrease in residence time in high temperature region. Furthermore, the
thermal and prompt mechanisms were evaluated with equivalence ratio for two calculation methods. The conventional
methods ignore the interaction of coupled mechanism of thermal and prompt NOx. The reaction path diagram was
introduced to understand effective reaction pathways in various conditions.
Keyword :
CHEMKIN; Counterflow premixed flame; Thermal NOx; Prompt NOx
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